The UN numbers range from UN0401 to UN0500
| UN Number | Class | Proper Shipping Name |
| UN 0401 | 1 | Dipicryl sulfide, dry or wetted with less than 10 percent water, by mass |
| UN 0402 | 1 | Ammonium perchlorate |
| UN 0403 + UN 0404 | 1 | Flares, aerial |
| UN 0405 | 1 | Cartridges, signal |
| UN 0406 | 1 | Dinitrosobenzene |
| UN 0407 | 1 | Tetrazol-1-acetic acid |
| UN 0408 - UN 0410 | 1 | Fuzes, detonating, with protective features |
| UN 0411 | 1 | Pentaerythrite tetranitrate or Pentaerythritol tetranitrate or PETN, with not less than 7 percent wax by mass |
| UN 0412 | 1 | Cartridges for weapons, with bursting charge |
| UN 0413 | 1 | Cartridges for weapons, blank |
| UN 0414 | 1 | Charges, propelling, for cannon |
| UN 0415 | 1 | Charges, propelling |
| UN 0417 | 1 | Cartridges for weapons, inert projectile or Cartridges, small arms |
| UN 0418 + UN 0419 | 1 | Flares, surface |
| UN 0420 + UN 0421 | 1 | Flares, aerial |
| UN 0424 + UN 0425 | 1 | Projectiles, inert with tracer |
| UN 0426 + UN 0427 | 1 | Projectiles, with burster or expelling charge |
| UN 0428 - UN 0432 | 1 | Articles, pyrotechnic for technical purposes |
| UN 0433 | 1 | Powder cake, wetted or Powder paste, wetted with not less than 17 percent alcohol by mass |
| UN 0434 + UN 0435 | 1 | Projectiles, with burster or expelling charge |
| UN 0436 - UN 0438 | 1 | Rockets, with expelling charge |
| UN 0439 - UN 0441 | 1 | Charges, shaped, without detonator |
| UN 0442 - UN 0445 | 1 | Charges, explosive, commercial without detonator |
| UN 0446 + UN 0447 | 1 | Cases, combustible, empty, without primer |
| UN 0448 | 1 | 5-Mercaptotetrazol-1-acetic acid |
| UN 0449 | 1 | Torpedoes, liquid fueled, with or without bursting charge |
| UN 0450 | 1 | Torpedoes, liquid fueled, with inert head |
| UN 0451 | 1 | Torpedoes with bursting charge |
| UN 0452 | 1 | Grenades, practice, hand or rifle |
| UN 0453 | 1 | Rockets, line-throwing |
| UN 0454 | 1 | Igniters |
| UN 0455 | 1 | Detonators, non-electric, for blasting |
| UN 0456 | 1 | Detonators, electric, for blasting |
| UN 0457 - UN 0460 | 1 | Charges, bursting, plastics bonded |
| UN 0461 | 1 | Components, explosive train, n.o.s. |
| UN 0462 - UN 0472 | 1 | Articles, explosive, n.o.s. |
| UN 0473 - UN 0481 | 1 | Substances, explosive, n.o.s. |
| UN 0482 | 1 | Substances, explosive, very insensitive, n.o.s., or Substances, EVI, n.o.s. |
| UN 0483 | 1 | Cyclotrimethylenetrinitramine, desensitized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized |
| UN 0484 | 1 | Cyclotetramethylenetetranitramine, desensitized or Octogen, desensitized or HMX, desensitized |
| UN 0485 | 1 | Substances, explosive, n.o.s. |
| UN 0486 | 1 | Articles, explosive, extremely insensitive or Articles, EEI |
| UN 0487 | 1 | Signals, smoke |
| UN 0488 | 1 | Ammunition, practice |
| UN 0489 | 1 | Dinitroglycoluril or Dingu |
| UN 0490 | 1 | Nitrotriazolone or NTO |
| UN 0491 | 1 | Charges, propelling |
| UN 0492 + UN 0493 | 1 | Signals, railway track, explosive |
| UN 0494 | 1 | Jet, perforating guns, charged oil well, with detonator |
| UN 0495 | 1 | Propellant, liquid |
| UN 0496 | 1 | Octonal |
| UN 0497 | 1 | Propellant, liquid |
| UN 0498 + UN 0499 | 1 | Propellant, solid |
| UN 0500 | 1 | Detonator assemblies, non-electric for blasting |
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